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Metal-based direct hydrogen generation as unconventional high density energy
Shuo XU, Jing LIU
《能源前沿(英文)》 2019年 第13卷 第1期 页码 27-53 doi: 10.1007/s11708-018-0603-x
关键词: metal hydrogen generation hydrolysis metal water reaction clean energy
Yan Zhang, Jian Xiao, Qiying Lv, Shuai Wang
《化学科学与工程前沿(英文)》 2018年 第12卷 第3期 页码 494-508 doi: 10.1007/s11705-018-1732-9
Electrolytic water splitting has been considered as a promising technology to produce highly pure H2 by using electrical power produced from wind, solar energy or other fitful renewable energy resources. Combining novel self-supporting structure and high-performance transition metal phosphides (TMP) shows substantial promise for practical application in water splitting. In this review, we try to provide a comprehensive analysis of the design and fabrication of various self-supported TMP electrodes for hydrogen evolution reaction, which are divided into three categories: catalysts growing on carbon-based substrates, catalysts growing on metal-based substrates and freestanding catalyst films. The material structures together with catalytic performances of self-supported electrodes are presented and discussed. We also show the specific strategies to further improve the catalytic performance by elemental doping or incorporation of nanocarbons. The simple and one-step methods to fabricate self-supported TMP electrodes are also highlighted. Finally, the challenges and perspectives for self-supported TMP electrodes in water splitting application are briefly discussed.
关键词: transition metal phosphide self-supported electrode electrocatalysis hydrogen evolution reaction
《化学科学与工程前沿(英文)》 2021年 第15卷 第6期 页码 1487-1499 doi: 10.1007/s11705-021-2085-3
关键词: MOF derivative graphene electrocatalyst oxygen reduction reaction oxygen evolution reaction hydrogen evolution reaction
Solid-state NMR for metal-containing zeolites: From active sites to reaction mechanism
Xingling Zhao, Jun Xu, Feng Deng
《化学科学与工程前沿(英文)》 2020年 第14卷 第2期 页码 159-187 doi: 10.1007/s11705-019-1885-1
关键词: metal-containing zeolites solid-state NMR active site host-guest interaction reaction mechanism
《环境科学与工程前沿(英文)》 2022年 第16卷 第7期 doi: 10.1007/s11783-021-1501-8
• Oxidation of methotrexate by high-valent metal-oxo species was first explored.
关键词: Anticancer drugs High-valent metal-oxo species Oxidation kinetics Reaction mechanisms Multi-endpoint toxicity
Structural engineering of transition metal-based nanostructured electrocatalysts for efficient water
Yueqing Wang, Jintao Zhang
《化学科学与工程前沿(英文)》 2018年 第12卷 第4期 页码 838-854 doi: 10.1007/s11705-018-1746-3
关键词: water splitting structure engineering metal organic framework ion exchange synergistic effect hybrid structure conductive supports
《能源前沿(英文)》 2022年 第16卷 第3期 页码 483-491 doi: 10.1007/s11708-022-0813-0
关键词: three-dimensional molybdenum nanomaterials hydrogen evolution reaction oxygen evolution reaction overall water splitting
Review on research and application of mesoporous transitional metal oxides in water treatment
Minghao SUI, Lei SHE
《环境科学与工程前沿(英文)》 2013年 第7卷 第6期 页码 795-802 doi: 10.1007/s11783-013-0521-4
关键词: mesoporous materials transitional metal oxides catalysis adsorption water treatment
Man ZHANG,Feng HE,Dongye ZHAO
《环境科学与工程前沿(英文)》 2015年 第9卷 第5期 页码 888-896 doi: 10.1007/s11783-015-0774-1
关键词: catalytic hydrodechlorination electronic structure metal nanoparticles reaction mechanisms
《化学科学与工程前沿(英文)》 2023年 第17卷 第5期 页码 570-580 doi: 10.1007/s11705-022-2247-y
关键词: bimetallic metal–organic frameworks bifunctional electrocatalyst density functional theory oxygen reduction reaction oxygen evolution reaction
Fluoride ions adsorption from water by CaCO enhanced Mn–Fe mixed metal oxides
《化学科学与工程前沿(英文)》 2023年 第17卷 第2期 页码 236-248 doi: 10.1007/s11705-022-2193-8
关键词: mesoporous materials metal oxides fluoride ion adsorption mechanism
《化学科学与工程前沿(英文)》 2023年 第17卷 第12期 页码 1962-1972 doi: 10.1007/s11705-023-2359-z
关键词: water gas shift iron copper bimetallic catalysts ceria hydrogen
Metal-free, carbon-based catalysts for oxygen reduction reactions
Zhiyi Wu,Zafar Iqbal,Xianqin Wang
《化学科学与工程前沿(英文)》 2015年 第9卷 第3期 页码 280-294 doi: 10.1007/s11705-015-1524-4
关键词: oxygen reduction reaction electrocatalysis metal-free carbon-based polynitrogen
Layered double hydroxide-based core-shell nanoarrays for efficient electrochemical water splitting
Wenfu Xie, Zhenhua Li, Mingfei Shao, Min Wei
《化学科学与工程前沿(英文)》 2018年 第12卷 第3期 页码 537-554 doi: 10.1007/s11705-018-1719-6
Electrochemical water splitting is an efficient and clean strategy to produce sustainable energy productions (especially hydrogen) from earth-abundant water. Recently, layered double hydroxide (LDH)-based materials have gained increasing attentions as promising electrocatalysts for water splitting. Designing LDHs into hierarchical architectures (e.g., core-shell nanoarrays) is one of the most promising strategies to improve their electrocatalytic performances, owing to the abundant exposure of active sites. This review mainly focuses on recent progress on the synthesis of hierarchical LDH-based core-shell nanoarrays as high performance electrocatalysts for electrochemical water splitting. By classifying different nanostructured materials combined with LDHs, a number of LDH-based core-shell nanoarrays have been developed and their synthesis strategies, structural characters and electrochemical performances are rationally described. Moreover, further developments and challenges in developing promising electrocatalysts based on hierarchical nanostructured LDHs are covered from the viewpoint of fundamental research and practical applications.
关键词: layered double hydroxides (LDHs) core-shell nanoarrays oxygen evolution reaction (OER) hydrogen evolution reaction (HER) photoelectrochemical water splitting (PEC)
Tianxiang XIA, Xuehua LIU
《环境科学与工程前沿(英文)》 2011年 第5卷 第2期 页码 236-242 doi: 10.1007/s11783-010-0218-8
标题 作者 时间 类型 操作
Self-supported transition metal phosphide based electrodes as high-efficient water splitting cathodes
Yan Zhang, Jian Xiao, Qiying Lv, Shuai Wang
期刊论文
Graphene-reinforced metal-organic frameworks derived cobalt sulfide/carbon nanocomposites as efficient
期刊论文
Solid-state NMR for metal-containing zeolites: From active sites to reaction mechanism
Xingling Zhao, Jun Xu, Feng Deng
期刊论文
identification and toxicity change during oxidation of methotrexate by ferrate and permanganate in water
期刊论文
Structural engineering of transition metal-based nanostructured electrocatalysts for efficient water
Yueqing Wang, Jintao Zhang
期刊论文
route to achieve MoSe-NiSe on nickel foam as efficient dual functional electrocatalysts for overall water
期刊论文
Review on research and application of mesoporous transitional metal oxides in water treatment
Minghao SUI, Lei SHE
期刊论文
Catalytic activity of noble metal nanoparticles toward hydrodechlorination: influence of catalyst electronic
Man ZHANG,Feng HE,Dongye ZHAO
期刊论文
cluster-based organic frameworks as highly active electrocatalysts for oxygen reduction and oxygen evolution reaction
期刊论文
Enhanced activity of bimetallic Fe-Cu catalysts supported on ceria toward water gas shift reaction: synergistic
期刊论文
Metal-free, carbon-based catalysts for oxygen reduction reactions
Zhiyi Wu,Zafar Iqbal,Xianqin Wang
期刊论文
Layered double hydroxide-based core-shell nanoarrays for efficient electrochemical water splitting
Wenfu Xie, Zhenhua Li, Mingfei Shao, Min Wei
期刊论文